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Material Safety Data Sheet

acc. to OSHA and ANSI
  Printing date 05/30/2000 Reviewed on 05/05/2000  
  •   1 Identification of substance:

    • Product details:


    • Trade name: Titanium (IV) 2-ethylhexoxide


    • Stock number: 77107


    • Manufacturer/Supplier:

      • Alfa Aesar, A Johnson Matthey Company
      Johnson Matthey Catalog Company, Inc.
      30 Bond Street
      Ward Hill, MA 01835-8099
      Emergency Phone: (978) 521-6300
      CHEMTREC: (800) 424-9300
      Web Site: www.alfa.com

    • Information department: Health, Safety and Environmental Department

    • Emergency information:

      • During normal hours the Health, Safety and Environmental Department. After normal hours call Chemtrec at (800) 424-9300.
  •   2 Composition/Data on components:

    • Chemical characterization:

      •            Description: (CAS#)                                        
                  Titanium (IV) 2-ethylhexoxide (CAS# 1070-10-6), 100%
    • Identification number(s):

    • EINECS Number: 213-969-1
  •   3 Hazards identification

    • Hazard description: Xi Irritant

    • Information pertaining to particular dangers for man and environment

      • R 36/37/38 Irritating to eyes, respiratory system and skin.
      R 43       May cause sensitization by skin contact.
  •   4 First aid measures

    • After inhalation

      • Supply fresh air and to be sure call for a doctor.
      Supply fresh air. If required, provide artificial respiration. Keep patient warm.
      Seek immediate medical advice.
    • After skin contact

      • Immediately wash with water and soap and rinse thoroughly.
      Seek immediate medical advice.
    • After eye contact

      • Rinse opened eye for several minutes under running water. Then consult a doctor.
    • After swallowing Seek immediate medical advice.
  •   5 Fire fighting measures

    • Suitable extinguishing agents

      • CO2, sand, extinguishing powder. Do not use water.
    • For safety reasons unsuitable extinguishing agents Water

    • Special hazards caused by the material, its products of combustion or

      •   resulting gases:
      In case of fire, the following can be released:
      Carbon monoxide and carbon dioxide
      Metal oxide fume
    • Protective equipment:

      • Wear self-contained respirator.
      Wear fully protective impervious suit.
  •   6 Accidental release measures

    • Person-related safety precautions:

      • Wear protective equipment. Keep unprotected persons away.
      Ensure adequate ventilation
    • Measures for environmental protection:

      • Do not allow material to be released to the environment without proper governmental permits.
    • Measures for cleaning/collecting:

      • Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
      Ensure adequate ventilation.
    • Additional information:

      • See Section 7 for information on safe handling
      See Section 8 for information on personal protection equipment.
      See Section 13 for disposal information.
  •   7 Handling and storage


    • Handling

    • Information for safe handling:

      • Handle under dry protective gas.
      Keep container tightly sealed.
      Store in cool, dry place in tightly closed containers.
      Ensure good ventilation at the workplace.
    • Information about protection against explosions and fires:

      • No special measures required.

    • Storage

    • Requirements to be met by storerooms and receptacles:

      • No special requirements.
    • Information about storage in one common storage facility:

      • Do not store together with oxidizing and acidic materials.
      Store away from water/moisture.
      Store away from halogens.
    • Further information about storage conditions:

      • Store under dry inert gas.
      Protect from humidity and water.
      Keep container tightly sealed.
      Store in cool, dry conditions in well sealed containers.
  •   8 Exposure controls and personal protection

    • Additional information about design of technical systems:

      • Properly operating chemical fume hood designed for hazardous chemicals and having an average face velocity of at least 100 feet per minute.

      Components with limit values that require monitoring at the workplace:
      Not required.
    • Additional information: No data


    • Personal protective equipment

    • General protective and hygienic measures

      • The usual precautionary measures for handling chemicals should be followed.
      Keep away from foodstuffs, beverages and feed.
      Remove all soiled and contaminated clothing immediately.
      Wash hands before breaks and at the end of work.
      Avoid contact with the eyes and skin.
    • Breathing equipment:

      • Use suitable respirator when high concentrations are present.
    • Protection of hands: Impervious gloves

    • Eye protection:

      • Safety glasses
      Tightly sealed goggles
      Full face protection
    • Body protection: Protective work clothing.
  •   9 Physical and chemical properties:


    • Form: Liquid

    • Color: Light yellow

    • Odor: Not determined

    •                                      Value/Range  Unit    Method      

    • Change in condition

    • Melting point/Melting range:                  <-25 ° C

    • Boiling point/Boiling range:                   194 ° C

    • Sublimation temperature / start:   Not determined


    • Flash point:                                    71 ° C


    • Ignition temperature:              Not determined


    • Decomposition temperature:         Not determined


    • Danger of explosion:

      • Product does not present an explosion hazard.

    • Explosion limits:

    • Lower:                             Not determined

    • Upper:                             Not determined


    • Vapor pressure:                    Not determined


    • Density:               at   20 ° C           0.926 g/cm3


    • Solubility in / Miscibility with

    • Water:                             Reacts
  •  10 Stability and reactivity

    • Thermal decomposition / conditions to be avoided:

      • Decomposition will not occur if used and stored according to specifications.
    • Materials to be avoided:

      • Acids
      Oxidizing agents
      Water/moisture
      Halogens
    • Dangerous reactions No dangerous reactions known

    • Dangerous products of decomposition:

      • Carbon monoxide and carbon dioxide
      Metal oxide fume
  •  11 Toxicological information

    • Acute toxicity:

    • Primary irritant effect:

    • on the skin: Irritant to skin and mucous membranes.

    • on the eye: Irritating effect.

    • Sensitization: Sensitization possible through skin contact.

    • Subacute to chronic toxicity:

      • Titanium and titanium compounds are considered physiologically inert. There are no reported cases in the literature where titanium as such has caused human intoxication.
      Other than potential irritation (see above), no information on illness or injury from acute or chronic exposure to this product is available.
    • Additional toxicological information:

      • To the best of our knowledge the acute and chronic toxicity of this substance is not fully known.
      No classification data on carcinogenic properties of this material is available from the EPA, IARC, NTP, OSHA or ACGIH.
  •  12 Ecological information:

    • General notes:

      • Do not allow material to be released to the environment without proper governmental permits.
  •  13 Disposal considerations


    • Product:

    • Recommendation

      • Consult state, local or national regulations for proper disposal.

    • Uncleaned packagings:

    • Recommendation:

      • Disposal must be made according to official regulations.
  •  14 Transport information

      • Not a hazardous material for transportation.

    • DOT regulations:

    • Hazard class:             None


    • Land transport ADR/RID  (cross-border)

    • ADR/RID class:                None


    • Maritime transport IMDG:

    • IMDG Class:               None


    • Air transport ICAO-TI and IATA-DGR:

    • ICAO/IATA Class:          None


    • Transport/Additional information:

      • Not dangerous according to the above specifications.
  •  15 Regulations


    • Product related hazard informations:


    • Hazard symbols: Xi Irritant


    • Risk phrases:

      • 36/37/38 Irritating to eyes, respiratory system and skin.
      43       May cause sensitization by skin contact.

    • Safety phrases:

      • 24       Avoid contact with skin.
      26       In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
      37       Wear suitable gloves.

    • National regulations

      • All components of this product are listed in the U.S. Environmental Protection Agency Toxic Substances Control Act Chemical Substance Inventory.

    • Information about limitation of use:

      • For use only by technically qualified individuals.
  •  16 Other information:

      • Employers should use this information only as a supplement to other information gathered by them, and should make independent judgement of suitability of this information to ensure proper use and protect the health and safety of employees.  This information is furnished without warranty, and any use of the product not in conformance with this Material Safety Data Sheet, or in combination with any other product or process, is the responsibility of the user.

    • Department issuing MSDS: Health, Safety and Environmental Department.

    • Contact: Darrell R. Sanders